A Hierarchical SnO₂@Ni₆MnO₈ Composite for High-Capacity Lithium-Ion Batteries

Semiconductor-based composites are potential anodes for Li-ion batteries, owing to their high theoretical capacity and low cost. However, low stability induced by large volumetric change in cycling restricts the applications of such composites. Here, a hierarchical SnO₂@Ni₆MnO₈ composite comprising Ni₆MnO₈ nanoflakes growing on the surface of a three-dimensional (3D) SnO₂ is developed by a hydrothermal synthesis method, achieving good electrochemical performance as a Li-ion battery anode. The composite provides spaces to buffer volume expansion, its hierarchical profile benefits the fast transport of Li⁺ ions and electrons, and the Ni₆MnO₈ coating on SnO₂ improves conductivity. Compared to SnO₂, the Ni₆MnO₈ coating significantly enhances the discharge capacity and stability. The SnO₂@Ni₆MnO₈ anode displays 1030 mAh g^-1 at 0.1 A g^-1 and exhibits 800 mAh g^-1 under 0.5 A g^-1, along with high Coulombic efficiency of 95%. Furthermore, stable rate performance can be achieved, indicating promising applications.