Silica-based mesoporous ion-imprinted fluorescent sensors for the detection of Pb²⁺in aqueous environments

In this work, an environment-friendly core-shell material based on CDs@SiO₂as the core and mesoporous ion-imprinted layer as the shell was reported. As a highly sensitive and accurate fluorescent sensor for the detection of Pb²⁺in environmental water, the composition combined ion imprinting technology with quantum dots to selectively quench the fluorescence of CDs by metal coordination in the presence of Pb²⁺, and the visual change of gradually weakening blue color could be observed by the naked eye for visual detection. The mesoporous structure significantly improved the detection recognition rate of CDs@SiO₂@MIIPs.The molecularly imprinted sensor presented a favorable linear relationship over a Pb²⁺concentration range from 10 nmol l^-1to 100 nmol l^-1and a detection limit of 2.16 nmol l^-1for Pb²⁺. The imprinting factor of the CDs@SiO₂@MIIPs was 5.13. The sensor has a fast detection rate, is highly selective in the identification of Pb²⁺, and can be reused up to 10 times. The applicability of the method was evaluated by the determination of Pb²⁺in spiked environmental water samples with satisfactory results.