Carbon-encapsulated Co₂P/P-modified NiMoO₄ hierarchical heterojunction as superior pH-universal electrocatalyst for...

The development of hydrogen evolution reaction (HER) technology that operates stably in a wide potential of hydrogen (pH) range of electrolytes is particular important for large-scale hydrogen production. However, the rational design of low-cost and pH-universal electrocatalyst with high catalytic performance remains a huge challenge. Herein, Co₂P nanoparticles strongly coupled with P-modified NiMoO₄ nanorods are directly grown on nickel foam (NF) substrates through carbon layer encapsulation (denoted as C-Co₂P@P-NiMoO₄/NF) by hydrothermal, deposition, and phosphating processes. This novel kind of hierarchical heterojunction has abundant heterogeneous interfaces, strong electronic interactions, and optimized reaction kinetics, representing the highly-active pH-universal electrodes for HER. Remarkably, the C-Co₂P@P-NiMoO₄/NF catalyst shows excellent HER properties in acidic and basic electrolytes, where the overpotentials of 105 mV and 107 mV are applied to drive the current density of 100 mA cm^-2. In addition, a low overpotential of 177 mV at 100 mA cm^-2 along with high stability is realized in 1 M phosphate buffer solution (PBS), which is close to the state-of-the-art non-precious metal electrocatalysts. Our work not only provides a class of robust pH-universal electrocatalyst but also offers a novel way for the rational design of other heterogeneous materials bythe interface regulation strategy.