Treatment to surfactant containing wastewater with membrane distillation membrane with novel sandwich structure

Surfactant containing wastewater widely exists in textile industry, which hardly to be treated by membrane technology due to its high in salinity and wetting potential. In this study, PVDF membrane was modified by constructing a PDMS-SiO₂-PDMS "sandwich" structure on top of its surface via coating to achieve resistance to surfactant induced wetting. The "sandwich" layer was optimized based on the membrane performance during membrane distillation. Compared to the pristine PVDF membrane with contact angle of 92°, the water contact angle of the membrane with a "sandwich" layer of 0.44 μm increased to 153°. For the feed contained 0.5 wt% NaCl and 0.25 wt% surfactant, there was no membrane wetting occurred during the experiment period using the membrane with a "sandwich" structure, in comparison to the pristine PVDF membrane being wetted from beginning. For a challenge experiment to the developed membrane lasting for 100 h using a surfactant containing feed, there is no wetting sign observed and the stable flux is 20 kg·m^-2·h^-1.