Hybrid photocathode based on a Ni molecular catalyst and Sb₂Se₃ for solar H₂ production

We report a H₂ evolving hybrid photocathode based on Sb₂Se₃ and a precious metal free molecular catalyst. Through the use of a high surface area TiO₂ scaffold, we successfully increased the Ni molecular catalyst loading from 7.08 ± 0.43 to 45.76 ± 0.81 nmol cm^-2, achieving photocurrents of 1.3 mA cm^-2 at 0 V vs. RHE, which is 81-fold higher than the device without the TiO₂ mesoporous layer.