Effect of electronic structure of energy transfer in bimetallic Ru(II)/Os(II) complexes
Weijun Dai1, Shiwen Yu1, Ci Kong1
1College of Chemistry and Environmental Science, Qujing Normal University, Qujing 655011, China. jjliu302@163.com.
Abstract:
Novel monometallic (μ-LL')Ru, Ru(μ-LL'), homobimetallic Ru(μ-LL')Ru, and heterodimetallic Ru(μ-LL')Os and Os(μ-LL')Ru complexes based on two asymmetrical ligands LL' (where LL' = L1L1', L2L2') have been synthesized and characterized. Spectroscopic analysis indicates that all complexes exhibit intense spin-allowed ligand-centered (LC) transitions at 288 nm and Ru-based moderate spin-allowed MLCT absorption between 440-450 nm. The Ru(μ-LL')Os and Os(μ-LL')Ru dinuclear complexes show Os-based unit absorption in the range of 565-583 nm. The Ru-based units of the complexes present different emission intensities due to differing steric hindrance at the coordination sites of the two bridging ligands. The Os(μ-LL')Ru dinuclear complexes present weaker emission intensity than their parent monometallic complexes (μ-LL')Ru. These results indicate that the emission of Os(μ-LL')Ru dinuclear complexes is quenched by the Os(II)-based units.
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