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Intercalation-induced amorphous hydrated vanadium oxide for boosted aqueous Zn2+ storage
Duo Chen1,2, Boran Wang3, Xueliang Cui1
1Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China. chenduo@nuaa.edu.cn.
Abstract:
An amorphous hydrated vanadium oxide induced by Zn2+ intercalation in Mg-ion inserted V2O5·nH2O (MgVOH) is developed as a high-performance cathode for ZIBs. In particular, zinc pyrovanadate as the product of the second phase transition is found to suppress the dissolution issue of the vanadium species for the cathode to facilitate long lifespan.

