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Complex Effects of Hemp Fibers and Impact Modifiers in Multiphase Polypropylene Systems
Denis Mihaela Panaitescu1, Zina Vuluga1, Adriana Nicoleta Frone1
1Polymer Department, National Institute for Research and Development in Chemistry and Petrochemistry ICECHIM, 202 Splaiul Independentei, 060021 Bucharest, Romania.
This study enhances polypropylene/hemp fiber composites for automotive use by incorporating SEBS or SBS modifiers. SEBS improved toughness and elongation, while SBS enhanced stiffness, offering tailored properties for electrical vehicle parts.
Area of Science:
- Materials Science
- Polymer Science
- Composite Materials
Background:
- Polypropylene (PP) composites offer advantages but struggle to balance stiffness and toughness.
- Developing PP composites with both high stiffness and toughness is a manufacturing challenge.
- Natural fiber composites are increasingly explored for sustainable material applications.
Purpose of the Study:
- To investigate the effects of SEBS and SBS modifiers on PP/hemp fiber composites.
- To tailor mechanical properties of PP composites for electrical vehicle parts.
- To understand the role of maleated polypropylene (MAPP) in modifying composite interfaces.
Main Methods:
- Incorporation of poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) and poly(styrene-b-butadiene-b-styrene) (SBS) into PP/hemp fiber composites.
- Use of maleated polypropylene (MAPP) to control interfacial properties.
- Mechanical testing (Young's modulus, storage modulus, elongation at break, impact strength) and Scanning Electron Microscopy (SEM) analysis.
Main Results:
- SEBS and SBS modifiers exhibited distinct effects on mechanical properties.
- SEBS-containing composites showed greater elongation at break and impact strength.
- SBS-containing composites demonstrated higher Young's and storage moduli.
- SEM analysis revealed better dispersion and smaller particle size for SEBS compared to SBS.
Conclusions:
- SEBS and SBS act as effective impact modifiers, offering different property profiles for PP/hemp fiber composites.
- The choice of modifier (SEBS vs. SBS) allows for tailoring composite properties for specific automotive applications.
- These modified composites show potential as sustainable alternatives to traditional automotive materials.
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