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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Magnetically separable triazine-based Cu(ii)-vitamin B5 complex in nitromethane toward efficient heterogeneous
Farzaneh Karimi1, Masoumeh Jadidi Nejad1, Arefe Salamatmanesh1
1Chemistry Department, Tarbiat Modares University P.O. Box 14155-4838 Tehran Iran heydar_a@modares.ac.ir +98-21-82883455 +98-21-82883444.
Abstract:
In the current study, a highly efficient heterogeneous copper catalyst has been developed by supporting copper acetate on a magnetically separable triazine-vitamin B5 system. After the successful characterization of the prepared nanoparticles by various techniques such as FT-IR, FE-SEM, EDX/MAP, XRD, TEM, TGA, VSM, and ICP-OES, the catalytic efficiency of them were evaluated in the cyanation reaction of aryl halides in the presence of nitromethane as a non-toxic and cost-effective cyanation source. The cyanation products were obtained in desirable yields. Notably, the magnetic nanocatalyst can be easily recovered and reused at least five times without a significant decrease in its performance.
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