Organocalcium-Complex-Catalyzed Dehydrogenative Silylation and Mono/Dihydrosilylation Tandem Reactions of Terminal
Tao Li1, Ruixin Liu1, Xiaojuan Liu1
1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China.
Abstract:
In principle, catalytic dehydrogenative silylation and mono/dihydrosilylation tandem reactions of terminal alkynes with hydrosilanes provide gem-disilylated alkenes or gem-trisilylated alkanes, but very little progress has been made. Herein, we report organocalcium-complex-catalyzed dehydrogenative silylation and mono/dihydrosilylation tandem reactions of terminal alkynes with hydrosilanes in one pot, which produce gem-disilylated alkenes in moderate yields and gem-trisilylated alkanes in high yields. We also briefly demonstrate that the synthesized gem-disilylated alkenes can be easily transformed into other organosilanes.
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