Variation of nitrate and nitrite in condensable particulate matter from coal-fired power plants under the simulated...

In this work, condensation temperature, H₂O vapor, SO₂, SO₃ and NH₃ were studied to explore the formation mechanism of nitrate ions (NO₃^-) and nitrite ions (NO₂^-) in condensable particulate matter (CPM) discharged by ultra-low emission coal-fired power plants. Some important results were obtained: (i) The concentration of NO₃^- and NO₂^- increased with the decrease of condensation temperature, and H₂O vapor could also promote the formation of NO₃^- and NO₂^-. (ii) The effects of SO₂ and SO₃ varied at different saturated states of flue gas, which was caused by the redox reaction of SO₂ and NO_X or the formation of H₂SO₄. (iii) NH₃ could promote the nucleation of NO₃^- and NO₂^-, and the promotion effect also existed in the existence of SO₂ or SO₃. It is worth mentioning that SO₃ and SO₂ might synergistically inhibit the formation of NO₃^- and NO₂^-, regardless of the presence of NH₃. The research results would enrich peoples understanding of the chemical and physical characteristics of NO₃^- and NO₂^- in CPM and provide a basic reference for the control of CPM emitted from coal-fired power plants.