UPR/Titanium dioxide nanocomposite: Preparation, characterization and application in photon/neutron shielding

The aim of present investigation is to fabricate TiO₂ reinforced novel composites as an alternate nuclear radiation shields. Unsaturated polyester resin has been reinforced by the incorporation of different weight proportions of titanium dioxide (5, 10, 15 and 20 wt%) nanoparticles. Accordingly, mass and linear attenuation coefficients (μ_m & μ), half and tenth value layers (HVL & TVL), relaxation length (λ) and effective atomic numbers (Z_eff) have been computed. Gamma ray transmission set up has been employed for the determination of experimental μ_m values and consistency of experimental outcomes has been compared with the induced results from WinXCom program and Geant4 simulation code. Moreover, discrepancy of fast neutron removal cross section with the increasing TiO₂ content in the prepared composites has been studied. Additionally, structural properties in terms of XRD, SEM, RAMAN, FTIR and mechanical properties in terms of compressive strength have been analysed. The findings of this study revealed that the addition of TiO₂ nanoparticles improved the mechanical, nuclear shielding and structural properties of composites. The best gamma ray shielding competency has been showed by the highest TiO₂ addition (20%) composite. All in all, UPR + TiO2 composites have been identified as promising alternative radiation shielding candidates owning to their cost effectiveness, ease of processing, good dispersion and lightweightness.