Highly Fluorescent Supramolecular Nanoring Composed of Bent-Shaped Cyanostilbene Derivatives and Cucurbit[8]urils
Seong Il Kim1, Hyeong Ju Kim1, Soo Young Park1
1Department of Materials Science and Engineering and, Research Institute of Advanced Materials, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 08826 (Republic of, Korea.
Abstract:
Supramolecular organic frameworks (SOFs) made of organic guest molecule and cucurbit[8]uril (CB[8]) in aqueous solution have great potential for diverse applications. Herein, we designed highly fluorescent zero-dimensional (0D) nano-ring SOF with CB[8] as a host and novel bent-shaped cyanostilbene guest. This host-guest complex successfully formed macrocyclic hexamer and showed significantly enhanced fluorescence (ΦF =68 %) compared to non-assembled monomer (ΦF =2 %). Unlike other SOFs, this 0D SOF could be dispersed uniformly without bundling phenomenon in water.
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