Environmental formaldehyde sensing at room temperature by smartphone-assisted and wearable plasmonic nanohybrids

Formaldehyde is a toxic and carcinogenic indoor air pollutant. Promising for its routine detection are gas sensors based on localized surface plasmon resonance (LSPR). Such sensors trace analytes by converting tiny changes in the local dielectric environment into easily readable, optical signals. Yet, this mechanism is inherently non-selective to volatile organic compounds (like formaldehyde) and yields rarely detection limits below parts-per-million concentrations. Here, we reveal that chemical reaction-mediated LSPR with nanohybrids of Ag/AgO core-shell clusters on TiO₂ enables highly selective formaldehyde sensing down to 5 parts-per-billion (ppb). Therein, AgO is reduced by the formaldehyde to metallic Ag resulting in strong plasmonic signal changes, as measured by UV/Vis spectroscopy and confirmed by X-ray diffraction. This interaction is highly selective to formaldehyde over other aldehydes, alcohols, ketones, aromatic compounds (as confirmed by high-resolution mass spectrometry), inorganics, and quite robust to relative humidity changes. Since this sensor works at room temperature, such LSPR nanohybrids are directly deposited onto flexible wristbands to quantify formaldehyde between 40-500 ppb at 50% RH, even with a widely available smartphone camera (Pearson correlation coefficient r = 0.998). Such chemoresponsive coatings open new avenues for wearable devices in environmental, food, health and occupational safety applications, as demonstrated by an early field test in the pathology of a local hospital.