Colorimetric and visual determination of iodide ions via morphology transition of gold nanobipyramids

The gold nanobipyramids (Au NBPs) are widely used in the analytical detection of biochemistry due to their unique localized surface plasmon resonance (LSPR) properties. In our developed approach, I^- in kelp was detected by etching Au NBPs in the presence of IO₃^-. Under acidic conditions, IO₃^- reacted rapidly with I^- to form I₂, subsequently I₂ reacted with I^- to form the intermediate I₃^-. In the presence of CTAB, Au NBPs were etched by I₂ derived from I₃^-, resulting in a decrease in the aspect ratio of Au NBPs, to form a significant blue shift of LSPR longitudinal peak and color variation of colloid which changed from blue-green to magenta and could be employed to quantitatively detect the concentration of I^- with the naked eye. A linear relationship can be found between the LSPR peak changes with the I^- concentration in a wide range from 4.0 μM to 15.0 μM, and the sensitive limit of detection (LOD) was 0.2 μM for UV-vis spectroscopy and the obvious color changes with a visual LOD was 4.0 μM for the naked eye. Benefiting from the high specificity, the proposed colorimetric detection of I^- in kelp samples was achieved, indicating the available potential of the colorimetric detection for the determination of I^- in real samples. What's more, this detection procedure was time-saving and could avoid tedious procedures.