Synthesis of hierarchically structured Fe₃C/CNTs composites in a FeNC matrix for use as efficient ORR...

Fe-N-C has a high number of FeN active sites and has thus been regarded as a high-performance oxygen reduction reaction (ORR) catalyst, and combining Fe₃C with Fe-N-C typically boosts ORR activity. However, the catalytic mechanism remains unknown, limiting further research and development. In this study, a precipitation-solvothermal process was used in conjunction with pyrolysis to produce a series of Fe-N-C catalysts derived from a zeolitic imidazolate framework (ZIF) that was composited with Fe₃C. The prepared catalysts had a multiscale structure of ZIF-like carbon particles and rod-like structures, as well as bamboo-like carbon nanotubes (CNTs) and carbon layers wrapped with Fe₃C particles while a series of studies revealed the origin of the rod-like structures and Fe₃C phase. The hierarchical structure was beneficial to the enhanced electrocatalytic performance of catalysts for ORR. The optimal sample had the highest half-wave potential of 0.878 V vs. RHE, which was higher than that of commercial Pt/C (0.861 V vs. RHE). The ECSA of the optimal sample was 1.08 cm² μg^-1, with an electron transfer number close to 4, and functioning kinetics. The optimal sample exhibited high durability and methanol tolerance for the ORR. Finally, blocking different Fe active sites with coordination ions demonstrated that Fe(ii) was the main active site, indicating that Fe₃C primarily served as a cocatalyst to optimize the electron structure of Fe-N-C, thereby synergistically improving the ORR activity.