Broadband UV-Excitation and Red/Far-Red Emission Materials for Plant Growth: Tunable Spectrum Conversion in Eu³⁺,Mn⁴⁺...

Broadband ultraviolet (UV) excitation and red/far-red emission phosphors can effectively convert solar spectrum to enhance photosynthesis and promote morphogenesis in plants. Based on the above application requirements, Eu³⁺ single-doped LaAl_1-GaO₃ solid solutions and Eu³⁺,Mn⁴⁺ codoped LaAl_0.7Ga_0.3O₃ phosphors were designed and synthesized in this work. The LaAl_0.7Ga_0.3O₃:0.05Eu³⁺ (LAG:Eu³⁺) phosphor exhibits a strong charge transfer band (CTB) excitation and characteristic ⁵D₀ → ⁷F₂ transition red emission (619 nm), which is very similar to the luminescence properties of Eu³⁺-organic ligand compound (EuL₃). Rietveld refinement studies further revealed that the cation substitution disturbs the site symmetry. The optimal Eu³⁺, Mn⁴⁺ co-doped LaAl_0.7Ga_0.3O₃ (LAG:Eu,Mn) phosphor possesses a dual-band excitation spectrum in broadband ultraviolet (UVA, UVB) area and a dual-band emission spectrum within red/far-red area. Under the sunlight radiation, the real-time spectrum of luminous laminated glasses fabricated by coating the LAG:Eu,Mn phosphor shows the percentage of radiant intensity in the red/far-red region significantly increases, suggesting that the phosphor can be a promising candidate for solar spectral conversion in plant cultivation. We believe this work provides a new idea for developing novel broadband ultraviolet excitation and red/far-red emission phosphors.