Hybrid Heterostructures to Generate Long-Lived and Mobile Photocarriers in Graphene

We report the generation of long-lived and highly mobile photocarriers in hybrid van der Waals heterostructures that are formed by monolayer graphene, few-layer transition metal dichalcogenides, and the organic semiconductor F₈ZnPc. Samples are fabricated by dry transfer of mechanically exfoliated MoS₂ or WS₂ few-layer flakes on a graphene film, followed by deposition of F₈ZnPc. Transient absorption microscopy measurements are performed to study the photocarrier dynamics. In heterostructures of F₈ZnPc/few-layer-MoS₂/graphene, electrons excited in F₈ZnPc can transfer to graphene and thus be separated from the holes that reside in F₈ZnPc. By increasing the thickness of MoS₂, these electrons acquire long recombination lifetimes of over 100 ps and a high mobility of 2800 cm² V^-1 s^-1. Graphene doping with mobile holes is also demonstrated with WS₂ as the middle layers. These artificial heterostructures can improve the performance of graphene-based optoelectronic devices.