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Updated: Aug 9, 2025

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
Vanadium and Niobium MXenes-Bilayered V2 O5 Asymmetric Supercapacitors
Mohit Saraf1, Teng Zhang1, Timofey Averianov1
1A.J. Drexel Nanomaterials Institute, and Department of Materials Science and Engineering, Drexel University, Philadelphia, PA 19104, USA.
Abstract:
MXenes offer high metallic conductivity and redox capacitance that are attractive for high-power, high-energy storage devices. However, they operate limitedly under high anodic potentials due to irreversible oxidation. Pairing them with oxides to design asymmetric supercapacitors may expand the voltage window and increase the energy storage capabilities. Hydrated lithium preintercalated bilayered V2 O5 ( δ-Lix V2 O5 ·nH2 O) is attractive for aqueous energy storage due to its high Li capacity at high potentials; however, its poor cyclability remains a challenge. To overcome its limitations and achieve a wide voltage window and excellent cyclability, it is combined with V2 C and Nb4 C3 MXenes. Asymmetric supercapacitors employing lithium intercalated V2 C (Li-V2 C) or tetramethylammonium intercalated Nb4 C3 (TMA-Nb4 C3 ) MXenes as the negative electrode, and a δ-Lix V2 O5 ·nH2 O composite with carbon nanotubes as the positive electrode in 5 m LiCl electrolyte operate over wide voltage windows of 2 and 1.6 V, respectively. The latter shows remarkably high cyclability-capacitance retention of ≈95% after 10 000 cycles. This work highlights the importance of selecting appropriate MXenes to achieve a wide voltage window and a long cycle life in combination with oxide anodes to demonstrate the potential of MXenes beyond Ti3 C2 in energy storage.
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