Hybrid nanoarchitectonics of coal-derived carbon with oxidation-induced morphology-selectivity for high-performance...

Coal-derived porous carbon with a large specific surface area is a common electrode material for supercapacitors. Its deep and branched micropores, dense bulk morphology and amorphous structure have greatly limited its practical applications. Herein, hybrid carbon materials were obtained from coal through oxidation followed by activation. The method allows tuning the morphology, porosity, structure, and the degree of graphitization. The pre-oxidation with KMnO₄ can break raw coal into small hydrocarbon fragments, which deposit and grow on the surface of generated MnO during pyrolysis leading to hybrid carbon with mesoporous and graphitic nanostructures. Meanwhile, homogeneous etching of the carbon skeleton by the reaction intermediate of K₂CO₃ led to the formation of abundant active sites. Hence, the optimized sample exhibited a high capacitance of 333 F g^-1 at 1 A g^-1, an excellent rate capability with 58% capacitance retention at 100 A g^-1 and superior cycle durability in a three-electrode system. Besides, an assembled symmetric two-electrode device displayed a high energy density of 8.9 Wh·kg^-1 at 250 W·kg^-1. This work proposed a facile and rational synthesis strategy by balancing the tradeoff between active sites and intrinsic conductivity and thus provided a new avenue for the value-added utilization of coal.