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A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When the rates of the forward and reverse reactions are equal, the concentrations of the reactant and product species remain constant over time and the system is at equilibrium. A special double arrow is used to emphasize the reversible nature of the reaction. The relative concentrations of reactants and products in equilibrium systems vary greatly;...
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Oscillation and Reaction Board Techniques for Estimating Inertial Properties of a Below-knee Prosthesis
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Tuning nonequilibrium phase transitions with inertia.

Ahmad K Omar1, Katherine Klymko2, Trevor GrandPre3

  • 1Department of Materials Science and Engineering, University of California, Berkeley, California 94720, USA.

The Journal of Chemical Physics
|February 22, 2023
PubMed
Summary
This summary is machine-generated.

Inertia can drive active systems toward equilibrium-like states, suppressing phase separation and restoring crystallization. This finding offers a new perspective on controlling nonequilibrium transitions in driven matter.

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Area of Science:

  • Physics
  • Soft Matter Physics
  • Statistical Mechanics

Background:

  • Active systems, unlike equilibrium systems, exhibit unique behaviors driven by internal energy sources.
  • Inertia's role in active matter dynamics is often overlooked but can significantly impact system structure.
  • Nonequilibrium phenomena, such as motility-induced phase separation, challenge traditional thermodynamic principles.

Purpose of the Study:

  • To investigate the influence of particle inertia on the phase behavior of active systems.
  • To demonstrate how increasing inertia can lead to effective equilibrium-like states in driven systems.
  • To explore the underlying mechanisms and implications of inertia-induced transitions in active matter.

Main Methods:

  • Simulations of active Brownian spheres with varying inertia.
  • Analysis of phase separation, crystallization, and statistical properties.
  • Theoretical framework to explain the conversion of active stresses to passive-like stresses.

Main Results:

  • Increasing particle inertia suppresses motility-induced phase separation in active Brownian spheres.
  • Higher inertia restores equilibrium crystallization, mimicking passive systems.
  • Nonequilibrium patterns disappear in various driven systems with increasing inertia.
  • Effective temperature becomes density-dependent, a signature of residual nonequilibrium dynamics.

Conclusions:

  • Particle inertia is a crucial parameter that can drive active systems towards effective equilibrium states.
  • The phenomenon offers a mechanism to tune and potentially control nonequilibrium phase transitions.
  • Understanding inertia's role provides insights into the effective temperature concept in driven systems.