Rhodamine B dye degradation using used face masks-derived carbon coupled with peroxymonosulfate

Catalytic carbon materials from used face masks (UFM) activated by peroxymonosulfate (PMS) were developed for the degradation of rhodamine B (RhB) dye in aqueous solution. The UFM-derived carbon (UFMC) catalyst had a relatively large surface area as well as active functional groups and promoted the generation of singlet ¹O₂ and radicals from PMS, giving a high RhB degradation performance (98.1% after 3 h) in the presence of 3 mM PMS. The UFMC could degrade only 13.7% at a minimal RhB dose of 10^-5 M. The principal reactive oxygen species of sulphate (SO₄^•), hydroxyl radicals (^•OH), and singlet ¹O₂ were discovered using electron paramagnetic resonance and radical scavenger studies. Finally, a toxicological plant and bacterial study was performed to demonstrate the potential non-toxicity of the degraded RhB water sample.