Modulus watch: In situ determination of the gel modulus by timing the fluorescence color change

The gel modulus, a key parameter for gel materials, is traditionally determined by cumbersome rheometer. Recently, probe technologies occur to meet the requirements of in situ determination. Till now, in situ and quantitatively testing of gel materials with unabridged structure informations still remains a challenge. Here, we provide a facile, in situ approach to determine the gel modulus, by timing the aggregation of a doped fluorescence probe. The probe shows green emission during aggregation and shifts to blue once it forms aggregates. The higher modulus of the gel, the longer probe's aggregation time. Furthermore, a quantitative correlation of gel modulus with the aggregation time is established. The in situ method not only facilitates the scientific researches in the field of gels, but also provides a new approach for spatiotemporal materials.