Recyclable Magnetic Iron Immobilized onto Chitosan with Bridging Cu Ion for the Enhanced Adsorption of Methyl Orange

Chitosan (CS) is a natural and low-cost adsorbent for capturing metal ions and organic compounds. However, the high solubility of CS in acidic solution would make it difficult to recycle the adsorbent from the liquid phase. In this study, the CS/Fe₃O₄ was prepared via Fe₃O₄ nanoparticles immobilized onto a CS surface, and the DCS/Fe₃O₄-Cu was further fabricated after surface modification and the adsorption of Cu ions. The meticulously tailored material displayed the sub-micron size of an agglomerated structure with numerous magnetic Fe₃O₄ nanoparticles. During the adsorption of methyl orange (MO), the DCS/Fe₃O₄-Cu delivered a superior removal efficiency of 96.4% at 40 min, which is more than twice the removal efficiency of 38.7% for pristine CS/Fe₃O₄. At an initial MO concentration of 100 mg L^-1, the DCS/Fe₃O₄-Cu exhibited the maximum adsorption capacity of 144.60 mg g^-1. The experimental data were well explained by the pseudo-second-order model and Langmuir isotherm, suggesting the dominant monolayer adsorption. The composite adsorbent still maintained a large removal rate of 93.5% after five regeneration cycles. This work develops an effective strategy to simultaneously achieve high adsorption performance and convenient recyclability for wastewater treatment.