Pd-Catalyzed Photochemical Alkylative Functionalization of C═C and C═N Bonds
Ganesh Chandra Upreti1, Tavinder Singh1, Kirti Khanna1
1Department of Chemistry, IIT Kanpur, Kanpur 208016, Uttar Pradesh, India.
Abstract:
The development of excited-state palladium-catalyzed alkylative cyclization of acrylamides and the alkylation of quinoxalinones is described. The application of a variety of primary, secondary, and tertiary unactivated alkyl halides as alkyl radical precursors and the use of a simple catalyst system are the highlights of this reactivity manifold. The reactions exhibit wide scope, occur under mild conditions, and furnish the products in excellent yields.
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