Development of high-capacity surface-engineered MXene composite for heavy metal Cr (VI) removal from industrial...

The substantial quantity of Cr(VI) contaminants in the aqueous atmosphere is a major environmental fear that cannot be overlooked. For the first time, MXene and chitosan-coated polyurethane foam have been employed for wastewater treatment, including heavy metal ions (Cr (VI)) through a fixed-bed column study. It is also the most inexpensive, lightweight, and globally friendly material tested. The Mxene and chitosan-coated polyurethane foam hybrid materials were thoroughly investigated using FTIR (Fourier transform infrared), SEM (scanning electron microscope), XPS (X-ray photoelectron spectroscopy) and XRD (X-ray diffraction). The presence of the rough surface and the pore creation in the Mxene- MX₃@CS₃@PUF should rise its surface area, which is useful to interact the surface-active assembly of MX₃@CS₃@PUF and the Cr(VI) contaminations in the aqueous solution. With the help of the ion exchange mechanism and electrostatic contact, negatively charged MXene hexavalent ions were being adsorbed on the surface. MXene and chitosan have been coated on PUF foam in the form of three different layers, which shows the highest adsorption capacity, where up to ∼70% Cr (VI) was removed in the first 10 min and more than 60% elimination after 3 h when the metal ion concentration was 20 ppm. The electrostatic interaction between the negative charge MXene and the positive charge chitosan on the surface of PUF, which was absent in MX@PUF, is accountable for the high removal efficiency. This was done through a sequence of fixed-bed column studies, which took place in the continuous flowing of wastewater.