Effective degradation of tetracycline via recyclable free-standing three-dimensional copper-based graphene as a...

Water pollution by antibiotics is a serious and growing problem. Given this challenge, a free-standing three-dimensional (3D) reduced graphene oxide foam supported copper oxide nanoparticles (3D-rGO-Cu_xO) was synthesized using GO as a precursor and applied as an efficient persulfate activator for tetracycline (TC) degradation. The influences of Cu_xO mass, solution pH, persulfate dosage, and common anions on the TC degradation were investigated in detail. Analytical techniques indicated that the 3D-rGO-Cu_xO showed a cross-linking three-dimensional network structure, and Cu_xO particles with irregular shapes were uniformly loaded on graphene pore walls. The XPS and Auger spectra of Cu confirmed that Cu₂O was the main component in solid copper compounds. The addition of Cu_xO was vitally important for the activation of the oxidation system, and the removal rate reached 98% with a Cu_xO load of 7:1. The pH showed little influence on the activation effect on TC degradation. For common anions, Cl^- and CO₃^2- had little influence on the system, while humic acid had a great inhibitory effect. The EPR test and quenching experiment revealed that the active substances in the oxidative degradation process mainly include SO₄^-·, ·OH, ¹O₂, and reactive Cu(III). Additionally, the 3D-rGO-Cu_xO material proved highly stable according to the replicated test results and was promising for the remediation of antibiotic-contaminated water.