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Related Concept Videos

Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
479
Raman Spectroscopy: Overview01:20

Raman Spectroscopy: Overview

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The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and...
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UV–Vis Spectroscopy: Molecular Electronic Transitions01:16

UV–Vis Spectroscopy: Molecular Electronic Transitions

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In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this...
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Molecular Spectroscopy: Absorption and Emission01:14

Molecular Spectroscopy: Absorption and Emission

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Molecules possess discrete energy levels called quantum states. Unlike atoms, which have simpler energy levels, molecules possess additional rotational and vibrational energy levels.  Each energy level is separated by an energy gap, with the gaps between adjacent electronic, vibrational, and rotational levels varying significantly. The three types of energy levels in a diatomic molecule are shown in Figure 1.
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UV–Vis Spectrometers01:14

UV–Vis Spectrometers

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The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
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IR Absorption Frequency: Hybridization01:21

IR Absorption Frequency: Hybridization

733
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that...
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20 mJ, 1 ps Yb:YAG Thin-disk Regenerative Amplifier
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Selectable two-wavelength Nd:YVO4 Raman laser at 671 and 714 nm.

Cheng-Li Hsieh, Hsin-Jia Huang, Chun-Ling Chen

    Optics Letters
    |March 22, 2023
    PubMed
    Summary
    This summary is machine-generated.

    A new continuous wave (CW) laser offers selectable wavelengths at 671 and 714 nm. This compact laser system is efficient and suitable for laser spectroscopy applications.

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    Area of Science:

    • Optics and Photonics
    • Laser Physics

    Background:

    • Continuous wave (CW) lasers are crucial for various scientific applications.
    • Developing compact and efficient tunable laser sources remains an active research area.

    Purpose of the Study:

    • To develop a compact and efficient CW laser source with selectable dual wavelengths.
    • To achieve tunable second harmonic generation (SHG) and sum frequency generation (SFG) for specific output wavelengths.

    Main Methods:

    • Utilized an Nd-doped and an undoped YVO4 crystal for fundamental and Raman wave generation.
    • Employed a single Lithium Triborate (LBO) crystal with thermal tuning for selectable phase-matching.
    • Implemented SHG of 1342 nm and SFG of 1342 nm and 1525 nm.

    Main Results:

    • Achieved selectable CW laser output at 671 nm and 714 nm.
    • Obtained optimal output powers of 4.5 W at 671 nm and 1.8 W at 714 nm with 40 W pump power.
    • Demonstrated efficient thermal tuning for phase-matching in the LBO crystal.

    Conclusions:

    • A compact and efficient CW laser source with selectable dual wavelengths (671 nm and 714 nm) has been successfully developed.
    • The laser system exhibits practical utility for laser spectroscopy and other demanding applications.
    • The thermal tuning approach offers a reliable method for wavelength selection in nonlinear optical processes.