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Estrogen adsorption from an aqueous solution on the chitosan nanoparticles
Reza Davarnejad1, Kasra Sarvmeili1, Zahra Safari1
1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran.
International Journal of Biological Macromolecules
|March 29, 2023
Summary
Chitosan nanoparticles effectively remove ethinylestradiol from wastewater. Optimized conditions achieved 92.50% removal, demonstrating their potential as a sustainable adsorbent for estrogenic contaminants.
Area of Science:
- Environmental Science
- Materials Science
- Chemical Engineering
Background:
- Estrogenic compounds like ethinylestradiol pose risks to aquatic ecosystems.
- Wastewater treatment requires efficient and reusable adsorbents for estrogen removal.
Purpose of the Study:
- To investigate chitosan nanoparticles for ethinylestradiol removal from aqueous wastewater.
- To optimize adsorption conditions using response surface methodology.
Main Methods:
- Chitosan nanoparticles characterized by SEM, XRD, and FT-IR.
- Experimental design using Design Expert software (CCD under RSM) with four variables.
- Optimization of contact time, adsorbent dosage, pH, and initial concentration.
Main Results:
- Chitosan nanoparticles exhibited an adsorption capacity of 5.79 mg/g and surface area of 62 m²/g.
- Maximum estrogen removal of 92.50% achieved under optimal conditions.
- Langmuir isotherm and pseudo-second-order models accurately described the adsorption process.
Conclusions:
- Chitosan nanoparticles are efficient, reusable adsorbents for ethinylestradiol removal.
- Optimized parameters include 220 min contact time, 1.45 g/L dosage, pH 7.3, and 5.7 mg/L initial concentration.
- This study highlights a promising method for treating estrogen-contaminated wastewater.

