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Updated: Aug 3, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Recent advances in visible light-induced C(sp 3)-N bond formation
Mónica Rivas1,2,3, Vitalii Palchykov1,3, Xiangqing Jia1,3
1Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, TX, USA.
Abstract:
Synthetic chemists have long focused on selective C(sp 3)-N bond-forming approaches in response to the high value of this motif in natural products, pharmaceutical agents and functional materials. In recent years, visible light-induced protocols have become an important synthetic platform to promote this transformation under mild reaction conditions. These photo-driven methods rely on converting visible light into chemical energy to generate reactive but controllable radical species. This Review highlights recent advances in this area, mostly after 2014, with an emphasis placed on C(sp 3)-H bond activations, including amination of olefins and carbonyl compounds, and cross-coupling reactions.
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