Light-Programmed Bistate Colloidal Actuation Based on Photothermal Active Plasmonic Substrate

Active particles have been regarded as the key models to mimic and understand the complex systems of nature. Although chemical and field-powered active particles have received wide attentions, light-programmed actuation with long-range interaction and high throughput remains elusive. Here, we utilize photothermal active plasmonic substrate made of porous anodic aluminum oxide filled with Au nanoparticles and poly(N-isopropylacrylamide) (PNIPAM) to optically oscillate silica beads with robust reversibility. The thermal gradient generated by the laser beam incurs the phase change of PNIPAM, producing gradient of surface forces and large volume changes within the complex system. The dynamic evolution of phase change and water diffusion in PNIPAM films result in bistate locomotion of silica beads, which can be programmed by modulating the laser beam. This light-programmed bistate colloidal actuation provides promising opportunity to control and mimic the natural complex systems.