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Updated: Aug 3, 2025

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
Published on: May 15, 2015
A simulation study on the phase transition behavior of solid nitrogen under extreme conditions
Han Qin1, Sheng-Hai Zhu2, Zhen Jiao3
1School of Science, Key Laboratory of High Performance Scientific Computation, Xihua University, Chengdu 610039, China.
Solid nitrogen exhibits a re-entrant phase transition at 0 K under increasing pressure. Extremely low temperatures are key to inducing this phase transition and reversal in nitrogen.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Thermodynamics
Background:
- Investigating low-temperature phenomena in materials is crucial but challenging under high pressure.
- Understanding solid nitrogen phases requires exploring behavior at extreme conditions.
Purpose of the Study:
- To investigate the phase transitions of solid nitrogen (α-N2 and γ-N2) at 0 K under varying pressures.
- To determine the role of extremely low temperatures in inducing phase transitions and reversals.
Main Methods:
- Calculations of phonon spectrum for solid nitrogen phases.
- Gibbs free energy calculations under different pressure conditions.
Main Results:
- Solid nitrogen (α-N2 and γ-N2) exhibits a re-entrant phase transition at 0 K as pressure increases.
- Extremely low temperatures are identified as the primary condition for inducing these phase transitions and reversals.
Conclusions:
- The study reveals a novel re-entrant phase transition in solid nitrogen at 0 K.
- Low temperatures are critical for driving phase transitions and phase reversals in nitrogen under pressure.
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