Plasmonic Perfect Absorber Utilizing Polyhexamethylene Biguanide Polymer for Carbon Dioxide Gas Sensing Application

In this paper a perfect absorber with a photonic crystal cavity (PhC-cavity) is numerically investigated for carbon dioxide (CO₂) gas sensing application. Metallic structures in the form of silver are introduced for harnessing plasmonic effects to achieve perfect absorption. The sensor comprises a PhC-cavity, silver (Ag) stripes, and a host functional material-Polyhexamethylene biguanide polymer-deposited on the surface of the sensor. The PhC-cavity is implemented within the middle of the cell, helping to penetrate the EM waves into the sublayers of the structure. Therefore, corresponding to the concentration of the CO₂ gas, as it increases, the refractive index of the host material decreases, causing a blue shift in the resonant wavelength and vice versa of the device. The sensor is used for the detection of 0-524 parts per million (ppm) concentration of the CO₂ gas, with a maximum sensitivity of 17.32 pm (pico meter)/ppm achieved for a concentration of 366 ppm with a figure of merit (FOM) of 2.9 RIU^-1. The four-layer device presents a straightforward and compact design that can be adopted in various sensing applications by using suitable host functional materials.