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Thermal and Radiation Stability in Nanocrystalline Cu
Marie Thomas1, Heather Salvador2, Trevor Clark3,4
1Metallurgical and Materials Engineering Department, Colorado School of Mines, Golden, CO 80401, USA.
Nanomaterials (Basel, Switzerland)
|April 13, 2023
Summary
Nanocrystalline metals offer radiation shielding but can grow during irradiation. This review highlights inconsistencies in understanding grain boundary interactions in copper, recommending standardized evaluations for better stability insights.
Area of Science:
- Materials Science
- Nuclear Engineering
- Metallurgy
Background:
- Nanocrystalline metals, with high grain boundary volume, are promising for radiation environments as defect sinks.
- Grain growth under irradiation and elevated temperatures limits the application of nanocrystalline metals.
- Limited understanding of irradiation-grain boundary interactions in pure metals hinders progress.
Purpose of the Study:
- To critically review existing studies on irradiation and thermal stability in nanocrystalline copper (Cu) and dilute Cu-based alloys.
- To identify and discuss the sources of discrepancies in interpreting irradiation-grain boundary interactions.
- To provide recommendations for a more unified mechanistic understanding of grain size stability under irradiation.
Main Methods:
- Comprehensive literature review of studies on nanocrystalline copper and dilute copper alloys.
- Critical analysis of irradiation environments and materials processing variations.
- Comparative assessment of reported irradiation-grain boundary interactions.
Main Results:
- Significant differences exist in the interpretation of irradiation-grain boundary interactions across studies.
- Variability in irradiation conditions and materials processing are primary sources of these discrepancies.
- Nanocrystalline copper exhibits complex behavior regarding grain growth under irradiation.
Conclusions:
- A unified understanding of grain boundary behavior in nanocrystalline metals under irradiation is lacking.
- Standardized evaluation methods are crucial for comparing results across different processing and irradiation conditions.
- Further research focusing on standardized evaluations will enhance the development of radiation-tolerant nanocrystalline materials.

