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Updated: Aug 2, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Melting of a macroscale binary Coulombic crystal.
Sarah Battat1, David A Weitz1,2,3, George M Whitesides4
1John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA. weitz@seas.harvard.edu.
This study shows that impurities do not affect the melting of two-dimensional binary Coulombic crystals. Instead, shear-induced melting occurs from the edges due to agitation, with some areas remaining ordered.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Statistical Mechanics
Background:
- Melting of 2D crystals in thermal equilibrium is well-understood.
- Melting behavior of out-of-equilibrium 2D systems remains largely unresolved.
- Coulombic crystals offer a model for studying phase transitions due to tunable interactions.
Purpose of the Study:
- To investigate the melting dynamics of a 2D binary Coulombic crystal under shear.
- To determine the influence of impurities on the melting process.
- To clarify the mechanisms of shear-induced melting in systems with long-range interactions.
Main Methods:
- Fabrication of a 2D binary Coulombic crystal using tribocharged nylon and polytetrafluoroethylene (PTFE) beads.
- Induction of melting via agitation using an orbital shaker.
- Comparison of melting behavior in pure and impurity-doped (gold-coated nylon beads) crystals.
Main Results:
- Impurities were found to have no significant effect on the crystal's melting behavior.
- Shear-induced melting initiated from the crystal edges due to collisions with the container.
- Localized ordering persisted in some regions due to electrostatic interactions and favorable collisions.
Conclusions:
- The study clarifies the melting mechanisms of sheared 2D Coulombic crystals, highlighting the role of persistent long-range interactions.
- The findings suggest that specific conditions can render such materials resistant to disorder.
- This research provides insights into the stability and phase transitions of out-of-equilibrium condensed matter systems.
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