Related Experiment Video
Updated: Aug 2, 2025

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application
Published on: March 8, 2019
Synthesis and characterization of low surface energy thermoplastic polyurethane elastomers based on
Jie Sun1, Xiaobin Zou1, Zhiqian Xu1
1School of Materials Science and Engineering, Beijing Institute of Technology Beijing 100081 China gzandlsy@bit.edu.cn.
Abstract:
Organosilicon modified polyurethane elastomers (Si-MTPUs) were synthesized in order to improve the anti-graffiti property of thermoplastic polyurethane elastomers (TPUs). Si-MTPUs were prepared from polydimethylsiloxane (PDMS) and polytetramethylene glycol (PTMG) as mixed soft segment, 1,4-butanediol (BDO) and imidazole salt ionic liquid N-glyceryl-N-methyl imidazolium chloride ([MIMl,g]Cl) used as chain extender, and 4,4'-dicyclohexylmethane diisocyanate (HMDI). The structure, thermal stability, mechanical properties and physical crosslinking density of Si-MTPUs were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA), mechanical test and low field nuclear magnetic resonance. Surface energy and water absorption were characterized by static contact angle test and water resistance test, and anti-graffiti and self-cleaning properties were characterized with water, milk, ink, lipstick, oily markers and spray paint. It was found that the mechanical properties of Si-MTPU-10 with the content of PDMS 10 wt% were optimized, with a maximum tensile strength of 32.3 MPa and elongation at break of 656%. Surface energy reached the minimum value of 23.1 mN m-1 with the best anti-graffiti performance, which no longer decreased with the increase of PDMS contents. This work provides novel idea and strategy for the preparation of low surface energy TPUs.
Related Concept Videos
Characteristics and Nomenclature of Homopolymers
Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Polymer Classification: Architecture
Polymer Classification: Stereospecificity
Molecular Weight of Step-Growth Polymers
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)

