Near-Infrared Light Responsive Surface with Switchable Wettability in Microstructure and Surface Chemistry

Intelligent surfaces with reversibly switchable wettability have recently drawn considerable attention. One typical strategy to obtain such a surface is to change the surface chemistry or the microstructure. Herein, we report a new smart surface for which the wettability was controlled by both the surface chemistry and microstructure. Various wetting states were reversibly and precisely controlled through heating, pressing, NIR irradiation, and oxygen plasma treatment. The excellent shape memory characteristics of shape memory polyurethane (SMPU) and the controlled release of hydrophobic/hydrophilic oxygen-containing functional groups contributed to this ability. Microcapsules were used to design these smart surfaces. They controlled the release of a fluorinated alkyl silane (FAS) through shell melting, changed the surface composition, and played a decisive role in protecting the FAS against hydrolysis and evaporation to ensure that the surface's wettability is recyclable. Controlling of the surface chemistry or microstructure was repeated for at least 19 or 16 cycles, respectively, which indicated excellent repeatability compared to other smart surfaces. Based on the excellent controllability, the surface exhibited multiple functions, such as liquid directional transport and coefficient of friction control. In addition, it maintained this extraordinary ability under harsh environments owing to the great stability of the SMPU and adequate protection of the FAS by the microcapsules. With switchable wettability based on the surface chemistry and microstructure, this work provides a new principle for designing smart surfaces with wettability controlled in two ways.