Self-supporting network-structured MoS₂/heteroatom-doped graphene as superior anode materials for sodium storage

Layered graphene and molybdenum disulfide have outstanding sodium ion storage properties that make them suitable for sodium-ion batteries (SIBs). However, the easy and large-scale preparation of graphene and molybdenum disulfide composites with structural stability and excellent performance face enormous challenges. In this study, a self-supporting network-structured MoS₂/heteroatom-doped graphene (MoS₂/NSGs-G) composite is prepared by a simple and exercisable electrochemical exfoliation followed by a hydrothermal route. In the composite, layered MoS₂ nanosheets and heteroatom-doped graphene nanosheets are intertwined with each other into self-supporting network architecture, which could hold back the aggregation of MoS₂ and graphene effectively. Moreover, the composite possesses enlarged interlayer spacing of graphene and MoS₂, which could contribute to an increase in the reaction sites and ion transport of the composite. Owing to these advantageous structural characteristics and the heteroatomic co-doping of nitrogen and sulfur, MoS₂/NSGs-G demonstrates greatly reversible sodium storage capacity. The measurements revealed that the reversible cycle capacity was 443.9 mA h g^-1 after 250 cycles at 0.5 A g^-1, and the rate capacity was 491.5, 490.5, 453.9, 418.1, 383.8, 333.1, and 294.4 mA h g^-1 at 0.1, 0.2, 0.5, 1, 2, 5 and 10 A g^-1, respectively. Furthermore, the MoS₂/NSGs-G sample displayed lower resistance, dominant pseudocapacitive contribution, and faster sodium ion interface kinetics characteristic. Therefore, this study provides an operable strategy to obtain high-performance anode materials, and MoS₂/NSGs-G with favorable structure and excellent cycle stability has great application potential for SIBs.