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Updated: Aug 1, 2025
Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Aldehyde Olefination with Arylboroxines Enabled by Binary Rhodium Catalysis
Zihao Zhang1,2, Jie Jia2, Fangdong Hu1
1School of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, China.
Abstract:
A rhodium-catalyzed olefination of aliphatic aldehydes with arylboroxines is described. The simple rhodium(I) complex [Rh(cod)OH]2 without any external ligands or additives is able to catalyze the reaction in air and neutral conditions, allowing the construction of aryl olefins in an efficient manner with a good functional group tolerance. The mechanistic investigation illustrates that the binary rhodium catalysis is the key for the transformation, which involves a Rh(I)-catalyzed 1,2-addition and a Rh(III)-catalyzed elimination.
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