Search research articles

ABOUT JoVE

Overview Leadership Blog JoVE Help Center

AUTHORS

Publishing Process Editorial Board Scope & Policies Peer Review FAQ Submit

LIBRARIANS

Testimonials Subscriptions Access Resources Library Advisory Board FAQ

RESEARCH

JoVE Journal Methods Collections JoVE Encyclopedia of Experiments Archive

EDUCATION

JoVE Core JoVE Business JoVE Science Education JoVE Lab Manual Faculty Resource Center Faculty Site

Terms & Conditions of Use

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by

Same author

Jerry Alfred Fereiro.

Angewandte Chemie (International ed. in English)·2026

Same author

Deciphering the Transition From Tunneling to Band-Like Transport in Protein-Templated Biohybrid Junctions.

Angewandte Chemie (International ed. in English)·2026

Same author

Recent Advances in Inorganic Oxide-Based Resistive Random Access Memory: Challenges and Strategies for Practical Applications.

ChemPlusChem·2025

Same author

Exploring the role of counterions in the electrochromic performance of redox-active viologen.

Physical chemistry chemical physics : PCCP·2025

Same author

Turning Superparamagnetic Nanoparticles Into Ferromagnetic at Room Temperature via Molecular Functionalization for Magnetic Memory Applications.

Angewandte Chemie (International ed. in English)·2025

Same author

Acid vapor-induced enhanced electrical current rectification in phenothiazine-based electronic devices.

Chemical science·2025

Same journal

A trigger that feeds itself.

Nature reviews. Chemistry·2026

Same journal

Advances in electrochemical peptide synthesis and modification.

Nature reviews. Chemistry·2026

Same journal

Making chemistry sing with AI.

Nature reviews. Chemistry·2026

Same journal

Publisher Correction: Reprogramming CO<sub>2</sub> reduction through interfacial water.

Nature reviews. Chemistry·2026

Same journal

Hydrogen generation promoted by single-atom-based thermochemical catalysts.

Nature reviews. Chemistry·2026

Same journal

The phonon map of molecular qubits.

Nature reviews. Chemistry·2026

See all related articles

Search research articles

Related Experiment Video

Updated: Aug 1, 2025

Fabricating Nanogaps by Nanoskiving

Fabricating Nanogaps by Nanoskiving

Published on: May 13, 2013

Nanoscale molecular rectifiers.

Ritu Gupta¹, Jerry A Fereiro², Akhtar Bayat³

¹Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh, India.

Nature Reviews. Chemistry

|April 28, 2023

Summary

This summary is machine-generated.

Molecular rectifiers, crucial for molecular electronics, are now competitive with silicon devices due to recent advances in custom-designed molecular systems achieving high rectification ratios.

More Related Videos

A Standard and Reliable Method to Fabricate Two-Dimensional Nanoelectronics

A Standard and Reliable Method to Fabricate Two-Dimensional Nanoelectronics

Published on: August 28, 2018

Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates

Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates

Published on: June 18, 2013

Related Experiment Videos

Last Updated: Aug 1, 2025

Fabricating Nanogaps by Nanoskiving

Fabricating Nanogaps by Nanoskiving

Published on: May 13, 2013

A Standard and Reliable Method to Fabricate Two-Dimensional Nanoelectronics

A Standard and Reliable Method to Fabricate Two-Dimensional Nanoelectronics

Published on: August 28, 2018

Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates

Ultrahigh Density Array of Vertically Aligned Small-molecular Organic Nanowires on Arbitrary Substrates

Published on: June 18, 2013

Area of Science:

Molecular electronics
Condensed matter physics
Materials science

Background:

Achieving stable molecular rectifiers is a key goal in molecular electronics.
Previous research faced fundamental understanding and practical challenges.
Recent breakthroughs have significantly advanced the field.

Purpose of the Study:

To provide an overview and critical analysis of recent progress in molecular rectification.
To discuss rectification mechanisms and highlight key molecular systems.
To present an outlook for the future commercialization of molecular rectifiers.

Main Methods:

Review of single molecules, self-assembled monolayers, multilayers, heterostructures, and metal-organic frameworks.
Analysis of rectification mechanisms in various molecular architectures.
Evaluation of rectification ratios and performance metrics.

Main Results:

Custom-designed molecular systems now achieve rectification ratios exceeding 10⁵.
These molecular rectifiers show potential competitiveness with silicon-based devices.
Diverse molecular architectures exhibit promising rectification properties.

Conclusions:

Significant progress has been made in molecular rectification.
Molecular rectifiers are emerging as viable alternatives to traditional semiconductor devices.
The field shows promise for future commercial applications in electronics.