Silver and Gold Containing Compounds of p-Block Elements As Perspective Materials for UV Plasmonics

We present a review of phase formation tendencies, methods for preparation and optical properties of alloys and compounds from the binary systems of silver or gold with metals and metalloids from the p-block of the Periodic system of elements. Reference data about the homogeneity regions in the systems of interest, together with information about the crystalline structure of existing indexed compounds in them, is proposed and statistically analyzed. General background for the synthesis of intermetallic alloys and compounds, and the tendencies for their preparation for plasmonic purposes are presented. The high plasma frequency, ω_p of p-block metals makes their alloys with silver and gold an interesting object of study, due to the possibility of ω_p variation over a wide interval in the ultraviolet (UV) spectral region with a view to finding more efficient materials for excitation of a localized surface plasmon resonance (LSPR) necessary for various applications and techniques operating in this part of the electromagnetic spectrum. Unlike the alloys between the noble metals Cu, Ag, and Au, which form continuous series of solid solutions, different areas can be observed in the phase diagrams of the Ag(Au)-p-block systems, containing solid solutions, intermetallic compounds, and heterogeneous mixtures. The ability to vary the plasma frequency of solid solutions, like the alloys between the noble metals Cu, Ag, and Au, is the reason to pay attention to the compositions of the Ag(Au-p-block systems that fall in these regions of their phase diagrams. The analysis of the published results for complex permittivity shows that the addition of small amounts of conductive p-block elements to noble metals reduces the energy gap for interband transitions and increases their plasmonic activity in the UV spectral range. The article analyzes the relationship between electrical resistivity and LSPR excitation efficiency, which shows that the intermetallic compounds from Ag(Au)-p-block systems with a well-ordered crystalline structure and good conductivity level can be more effective materials for UV plasmonics than the boundary solid solutions. Intermetallic compounds can be easily obtained in the form of bulk samples, thin films, and nanoparticles with controlled size and geometric shape. The spectral dependences of the plasmon efficiency of the intermetallic compounds, determined from their complex permittivity functions, show that they are promising materials for excitation of LSPR in the UV spectral region.