Related Experiment Video
Updated: Jul 31, 2025
Solution-Processed "Silver-Bismuth-Iodine" Ternary Thin Films for Lead-Free Photovoltaic Absorbers
Published on: September 27, 2018
Syntheses, structures, photoelectric properties and photocatalysis of iodobismuthate hybrids with lanthanide complex
Jiahua Zhang1, Xiao Yang1, Taohong Ren1
1College of Chemistry, Chemical Engineering and Materials Science, Soochow University, No. 199 Renai Road, Suzhou, 215123, P. R. China. jiadingxian@suda.edu.cn.
Abstract:
New iodobismuthate hybrids with lanthanide complex counter cations, [Ln(DMF)8][Bi2I9] (Ln = La (1), Eu (2)) and [Tb(DMF)8]2[Bi2I9]2 (3) (DMF = N,N-dimethylformamide), were prepared using solvated Ln(III) complexes formed in situ as structure-directing agents. The dimeric [Bi2I9]3- anion moieties of compounds 1-3 are aggregated by two slightly twisted BiI6 octahedra through face-sharing mode. The different crystal structures of 1-3 are due to the different I⋯I and C-H⋯I hydrogen bond interactions. Compounds 1-3 have narrow semiconducting band gaps at 2.23, 1.91 and 1.94 eV, respectively. Under Xe light irradiation, they exhibit steady photocurrent densities that are 1.81, 2.10 and 2.18 times higher than that of pure BiI3, respectively. Compounds 2 and 3 exhibited higher catalytic activities than 1 in the photodegradation of organic dyes CV and RhB, which are attributed to the stronger photocurrent response derived from the redox cycles of Eu3+/Eu2+ and Tb4+/Tb3+.
More Related Videos
09:09A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration
Published on: March 29, 2019
07:24Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Related Concept Videos
02:34Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
02:42Valence Bond Theory
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...