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"Noncovalent Interaction": A Chemical Misnomer That Inhibits Proper Understanding of Hydrogen Bonding, Rotation

Frank Weinhold1

  • 1Theoretical Chemistry Institute and Department of Chemistry, University of Wisconsin-Madison, Madison, WI 53706, USA.

Molecules (Basel, Switzerland)
|May 13, 2023
PubMed
Summary

The term "noncovalent interactions" is misleading for describing chemical bonding phenomena like hydrogen bonds. These interactions are fundamentally rooted in electronic covalency and resonance, necessitating a unified pedagogical approach to chemical bonding.

Keywords:
bond orderhydrogen bondingnatural bond orbital analysisnatural resonance theoryrotation barriersteric repulsionsupramolecular interactionσ/π-hole theory

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