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Temperature-Sensitive Modified Bentonite Based on NIPAM for Drilling Fluid: Experimental and Molecular Simulation
Yi Pan1, Xinyue Zhang1, Qianru Zhan1
1Department of Petroleum and Natural Gas Engineering College, Liaoning Petrochemical University, No. 1, West Section of Dandong Road, Wanghua District, Fushun 113001, China.
Molecules (Basel, Switzerland)
|May 13, 2023
Summary
Researchers developed temperature-sensitive modified bentonite (CMC-B-NIPAM) for drilling fluids. This material enhances drilling fluid stability by adapting rheological properties to temperature changes, improving safety and efficiency.
Area of Science:
- Materials Science
- Chemical Engineering
- Geology
Background:
- Bentonite is crucial for drilling fluid performance, but temperature fluctuations impact its effectiveness.
- Developing temperature-sensitive drilling fluid additives is significant for operational safety and economics.
Purpose of the Study:
- To synthesize and characterize a novel temperature-sensitive modified bentonite (CMC-B-NIPAM).
- To evaluate the performance of CMC-B-NIPAM in drilling fluid applications, focusing on temperature sensitivity and rheological properties.
Main Methods:
- Intercalation modification of calcium bentonite with sodium Carboxymethyl Cellulose (CMC) and grafting of N-isopropyl acrylamide (NIPAM) using silane coupling agent KH570.
- Optimization of synthesis parameters using a single-factor method.
- Characterization using X-ray Diffraction (XRD) and Fourier-Transform Infrared Spectroscopy (FTIR).
- Evaluation of temperature sensitivity, rheology, suspensibility, and expansion capacity.
- Molecular simulation to understand the synthesis mechanism.
Main Results:
- Successfully synthesized CMC-B-NIPAM with excellent temperature sensitivity.
- Optimized synthesis indexes for CMC-B and CMC-B-NIPAM.
- Observed steady flow and temperature thickening rheological properties in the 40-70 °C range.
- Demonstrated improved stability of drilling fluid flow patterns compared to traditional fluids.
Conclusions:
- CMC-B-NIPAM exhibits significant temperature sensitivity and desirable rheological behavior for drilling fluids.
- The developed modified bentonite enhances drilling fluid stability across varying temperatures.
- This advancement offers improved safety and economic benefits for water-based drilling operations.

