One-Dimensional Mn₅Si₃ Nanorods: Fabrication, Microstructure, and Magnetic Properties via a Novel Casting-Extraction...

This study presents a simple and innovative approach for producing one-dimensional Mn₅Si₃ nanorods through a casting-extraction process. In this technique, the Mn₅Si₃ nanorods were synthesized by reacting Mn and Si during brass solidification and extracted by electrochemical etching of the brass matrix. The effect of the cooling rate during casting on the nanorods' dimension, morphology, and magnetic properties was investigated. The results demonstrate that the prepared high-purity Mn₅Si₃ nanorods had a single-crystal D8₈ structure and exhibited ferromagnetism at room temperature. The morphology of the nanorods was an elongated hexagonal prism, and their preferred growth was along the [0001] crystal direction. Increasing the cooling rate from 5 K/s to 50 K/s lead to a decrease in the dimension of the nanorods but an increase in their ferromagnetism. At the optimal cooling rate of 50 K/s, the nanorods had a diameter and length range of approximately 560 nm and 2~11 μm, respectively, with a highest saturation magnetization of 7.5 emu/g, and a maximum coercivity of 120 Oe. These properties make the fabricated Mn₅Si₃ nanorods potentially useful for magnetic storage applications, and this study also provides a new perspective on the preparation of one-dimensional nanomaterials.