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Connecting Ruthenium Photocatalysis to 1,2-Dioxetane-Mediated Chemiluminescence: a Versatile Combination for Optical

Johannes Köckenberger1, Ryan Thurston1, Caroline Sauer1

  • 1Department of Chemistry and Pharmacy, Pharmaceutical Chemistry, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger-Str. 10, 91058, Erlangen, Germany.

Angewandte Chemie (International Ed. in English)
|May 15, 2023
PubMed

Keywords:
1,2-DioxetanesActinometryCIEELOptical StoragePhotocatalysis

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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
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