Stable and Active Au Catalyst Supported on CeMnO₃ Perovskite for Selective Oxidation of Glycerol

The selective oxidation of glycerol holds promise to transform glycerol into value-added chemicals. However, it remains a big challenge to achieve satisfactory selectivity toward the specific product at high conversion due to the multiple reaction pathways. Here, we prepare a hybrid catalyst via supporting Au nanoparticles on CeMnO₃ perovskite with a modest surface area, achieving promoted conversion of glycerol (90.1%) and selectivity of glyceric acid (78.5%), which are much higher than those of CeMnO solid-solution-supported Au catalysts with larger surface area and other Ce-based or Mn-based Au catalysts. The strong interaction between Au and CeMnO₃ perovskite facilitates the electron transfer from the B-site metal (Mn) in the CeMnO₃ perovskite to Au and stabilizes Au nanoparticles, which results in the enhanced catalytic activity and stability for glycerol oxidation. Valence band photoemission spectral analysis reveals that the uplifted d-band center of Au/CeMnO₃ promotes the adsorption of the glyceraldehyde intermediate on the catalyst surface, which benefits further oxidation of glyceraldehyde into glyceric acid. The flexibility of the perovskite support provides a promising strategy for the rational design of high-performance glycerol oxidation catalysts.