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Colloids03:22

Colloids

17.7K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.7K
Colloidal precipitates01:09

Colloidal precipitates

640
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
640
Colloids and Suspensions01:17

Colloids and Suspensions

1.9K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.9K
Coagulation01:06

Coagulation

342
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
342

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Related Experiment Video

Updated: Jul 30, 2025

Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning
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Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning

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Colloidal gelation with non-sticky particles.

Yujie Jiang1,2, Ryohei Seto3,4,5

  • 1Wenzhou Key Laboratory of Biomaterials and Engineering, Wenzhou Institute, University of Chinese Academy of Sciences, 325000, Wenzhou, Zhejiang, China. jiangyujie@ucas.ac.cn.

Nature Communications
|May 15, 2023
PubMed
Summary
This summary is machine-generated.

This study explores colloidal gel composites. Non-sticky particles influence gelation by altering effective volume fraction and introducing a competing lengthscale, controlling composite properties.

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Area of Science:

  • Materials Science
  • Colloid Science
  • Rheology

Background:

  • Colloidal gels are crucial in industry for their yield stress property, preventing sedimentation in formulations.
  • Real-world applications often involve composite gels with non-sticky inclusions, not just pure sticky colloids.
  • Understanding gelation in these complex systems is vital for material design.

Purpose of the Study:

  • To investigate the gelation process in binary composites of colloidal gels and non-sticky particles.
  • To determine how non-sticky inclusions affect gelation dynamics and final structure.
  • To identify the key parameters controlling gelation in such composite systems.

Main Methods:

  • Numerical simulations were employed to model the gelation process.
  • The study analyzed the influence of non-sticky particles on effective volume fraction and introduced lengthscales.
  • Different gel models were used to validate findings across a broad parameter range.

Main Results:

  • Non-sticky particles effectively confine gelation by modifying the volume fraction.
  • These particles introduce a new lengthscale that competes with cluster growth.
  • The ratio of these lengthscales dictates the interplay between confinement and competing length effects.

Conclusions:

  • The behavior of colloidal gel composites is governed by the interplay of effective volume fraction and competing lengthscales.
  • A potential universality exists across different classes of colloidal composites.
  • These findings offer insights for designing advanced materials with tailored rheological properties.