Biobased epoxy reactive diluents prepared from monophenol derivatives: effect on viscosity and glass transition...

The use of reactive diluents is undeniably of paramount importance to develop epoxy resins which would meet more demanding and restrictive processes and applications in terms of viscosity and glass transition temperature. In the context of developing resins with low carbon impacts, 3 natural phenols namely carvacrol, guaiacol and thymol were selected and converted into monofunctional epoxies using a general glycidylation procedure. Without advanced purification, the developed liquid-state epoxies showed very low viscosities of 16 cPs to 55 cPs at 20 °C, which could be further reduced to 12 cPs at 20 °C when purification by distillation is applied. The dilution effect of each reactive diluent on DGEBA's viscosity was also assessed for concentrations ranging from 5 to 20 wt% and compared to commercial and formulated DGEBA-based resin analogues. Interestingly, the use of these diluents reduced the initial viscosity of DGEBA by a factor of ten while maintaining glass transition temperatures above 90 °C. This article provides compelling evidence of the possibility of developing new sustainable epoxy resins with characteristics and properties that can be fine-tuned by only adjusting the reactive diluent concentration.