Insights into the multirole CoAl layered double hydroxide on boosting photoelectrochemical activity of hematite:...

As an important compound in many industrial and biological processes, hydrogen peroxide (H₂O₂) would cause harmfulness to human health at high concentration level. It thus is urgent to develop highly sensitive and selective sensors for practical H₂O₂ detection in the fields of water monitoring, food quality control, and so on. In this work, CoAl layered double hydroxide ultrathin nanosheets decorated hematite (CoAl-LDH/α-Fe₂O₃) photoelectrode was successfully fabricated by a facile hydrothermal process. CoAl-LDH/α-Fe₂O₃ displays the relatively wide linear range from 1 to 2000 μM with a high sensitivity of 132.0 μA mM^-1 cm^-2 and a low detection limit of 0.04 μM (S/N ≥ 3) for PEC detection of H₂O₂, which is superior to other similar α-Fe₂O₃-based sensors in literatures. The (photo)electrochemical characterizations, such as electrochemical impedance spectroscopy, Mott-Schottky plot, cyclic voltammetry, open circuit potential and intensity modulated photocurrent spectroscopy, were used to investigate the roles of CoAl-LDH on the improved PEC response of α-Fe₂O₃ toward H₂O₂. It revealed that, CoAl-LDH could not only passivate the surface states and enlarge the band bending of α-Fe₂O₃, but also could act as trapping centers for holes and followed by as active sites for H₂O₂ oxidation, thus facilitated the charge separation and transfer. The strategy for boosting PEC response would be help for the further development of semiconductor-based PEC sensors.